Phosphine-Free and Reusable Palladium Nanoparticles-Catalyzed Domino Strategy: Synthesis of Indanone Derivatives.

Saha, Rajib; Arunprasath, Dhanarajan; Sekar, Govindasamy

Saha, Rajib; Arunprasath, Dhanarajan; Sekar, Govindasamy.

Afiliación

Saha R; Department of Chemistry , Indian Institute of Technology Madras , Chennai , Tamil Nadu 600036 , India.
Arunprasath D; Department of Chemistry , Indian Institute of Technology Madras , Chennai , Tamil Nadu 600036 , India.
Sekar G; Department of Chemistry , Indian Institute of Technology Madras , Chennai , Tamil Nadu 600036 , India.

J Org Chem ; 83(8): 4692-4702, 2018 04 20.

Article en En | MEDLINE | ID: mdl-29607641

RESUMEN

The carbene migratory insertion involving a domino reaction by highly stable, reusable, and binaphthyl-stabilized Pd-nanoparticles (Pd-BNP) is disclosed. The reaction was catalyzed by 2 mol % of a heterogeneous Pd-BNP catalyst under external ligand-free conditions, and it afforded 3-aryl-substituted indanone derivatives in up to a 90% yield with exclusive E-selectivity. Furthermore, a one-pot reaction and derivatization of indanone derivatives were also successfully demonstrated.

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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: J Org Chem Año: 2018 Tipo del documento: Article País de afiliación: India Pais de publicación: Estados Unidos

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