Unraveling the mystery of "tech red" - a volatile technetium oxide.

Lawler, K V; Childs, B C; Czerwinski, K R; Sattelberger, A P; Poineau, F; Forster, P M

Lawler, K V; Childs, B C; Czerwinski, K R; Sattelberger, A P; Poineau, F; Forster, P M.

Afiliación

Lawler KV; Department of Chemistry and Biochemistry, University of Nevada Las Vegas, Las Vegas, NV 89154, USA. keith.lawler@unlv.edu Paul.Forster@unlv.edu.

Chem Commun (Camb) ; 54(10): 1261-1264, 2018 Jan 31.

Article en En | MEDLINE | ID: mdl-29340381

RESUMEN

We show that a Tc2O5 molecular species is the likely identity of an unknown volatile oxide which has remained uncharacterized for 50+ years. Exploration of this molecule's absorption spectra and intermolecular self-interactions provides a close match to experimental data and an explanation for volatility and resistance to crystallization.

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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Chem Commun (Camb) Asunto de la revista: QUIMICA Año: 2018 Tipo del documento: Article Pais de publicación: Reino Unido

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