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Humidity-Responsive ON/OFF Switching of Gas Inclusion by Using Cooperative Opening/Closing of Heterogeneous Crystalline Cavities in a Peptide NiII Macrocycle.
Miyake, Ryosuke; Kuwata, Chika; Ueno, Manami; Yamada, Teppei.
Afiliación
  • Miyake R; Department of Chemistry and Biochemistry, Graduate School of Humanities and Sciences, Ochanomizu University, 2-1-1, Otsuka, Bunkyo-ku, Tokyo, 112-8610, Japan.
  • Kuwata C; JST, PRESTO, 4-1-8, Honcho, Kawaguchi, Saitama, 332-0012, Japan.
  • Ueno M; Department of Chemistry and Biochemistry, Graduate School of Humanities and Sciences, Ochanomizu University, 2-1-1, Otsuka, Bunkyo-ku, Tokyo, 112-8610, Japan.
  • Yamada T; Department of Chemistry and Biochemistry, Graduate School of Humanities and Sciences, Ochanomizu University, 2-1-1, Otsuka, Bunkyo-ku, Tokyo, 112-8610, Japan.
Chemistry ; 24(4): 793-797, 2018 Jan 19.
Article en En | MEDLINE | ID: mdl-29193332
Humidity-responsive ON/OFF switching of CO2 inclusion, associated with cooperative structural changes of heterogeneous cavities in crystalline peptide NiII macrocycles, 1⋅NO3 , is demonstrated. The structural transformation between an "open form" and a "closed form" was caused by reversible water uptake into one of the cavities. The adsorption behavior of CO2 was studied with and without water vapor, combined with gas-composition analysis by using gas chromatography. The studies revealed that the open form of 1⋅NO3 adsorbs CO2 gas up to 34 g mol-1 , whereas the closed form adsorbs only a negligible amount of CO2 gas. Also, structural studies (X-ray and IR spectroscopies) and investigation of water-content dependence of CO2 adsorption revealed that the switching of gas inclusion occurred abruptly over a narrow range of water-vapor pressure and was caused by the cooperative opening of vacant space to give the open form due to the structural transformation by water uptake.
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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Chemistry Asunto de la revista: QUIMICA Año: 2018 Tipo del documento: Article País de afiliación: Japón Pais de publicación: Alemania
Texto completo
Añadir a Mi BVS
Imprimir
XML
PubMed Links
Buscar en Google

Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Chemistry Asunto de la revista: QUIMICA Año: 2018 Tipo del documento: Article País de afiliación: Japón Pais de publicación: Alemania