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Centrosymmetric (Hdima)2[Ge5B3O15(OH)] and Noncentrosymmetric Na4Ga3B4O12(OH): Solvothermal/Surfactant-Thermal Synthesis of Open-Framework Borogermanate and Galloborate.
Yu, Su-Juan; Gu, Xiang-Yu; Deng, Ting-Ting; Huang, Jian-Hao; Cheng, Jian-Wen; Yang, Guo-Yu.
Afiliación
  • Yu SJ; College of Chemistry and Life Sciences, Zhejiang Normal University , Jinhua, Zhejiang 321004, China.
  • Gu XY; College of Chemistry and Life Sciences, Zhejiang Normal University , Jinhua, Zhejiang 321004, China.
  • Deng TT; College of Chemistry and Life Sciences, Zhejiang Normal University , Jinhua, Zhejiang 321004, China.
  • Huang JH; College of Chemistry and Life Sciences, Zhejiang Normal University , Jinhua, Zhejiang 321004, China.
  • Cheng JW; College of Chemistry and Life Sciences, Zhejiang Normal University , Jinhua, Zhejiang 321004, China.
  • Yang GY; MOE Key Laboratory of Cluster Science, School of Chemistry and Chemical Engineering, Beijing Institute of Technology , Beijing 100081, China.
Inorg Chem ; 56(21): 12695-12698, 2017 Nov 06.
Article en En | MEDLINE | ID: mdl-29045136
Under solvothermal/surfactant-thermal conditions, two new open-framework borogermanate and galloborate, centrosymmetric (Hdima)2[Ge5B3O15(OH)] (1; dima = dimethylamine) and noncentrosymmetric Na4Ga3B4O12(OH) (2), were obtained and characterized. Compound 1 contains an unusual basket-shaped Ge5B3O18(OH) cluster and displays a 3D open-framework layered structure. Compound 2 shows an interrupted 3,4-connected network constructed by alternately linked BO3 units and Ga3+ ions and displays weak second-harmonic-generation response.

Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Inorg Chem Año: 2017 Tipo del documento: Article País de afiliación: China Pais de publicación: Estados Unidos

Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Inorg Chem Año: 2017 Tipo del documento: Article País de afiliación: China Pais de publicación: Estados Unidos