Shape effect-induced spiral superstructures in a self-assembled achiral disc-bent core amphiphile.

Gu, Kehua; Wen, Tao; Han, Mengying; Zhang, Wei; Zhang, Zhenyu; Zhou, Yu; Shen, Zhihao; Fan, Xinghe; Ho, Rong-Ming

Gu, Kehua; Wen, Tao; Han, Mengying; Zhang, Wei; Zhang, Zhenyu; Zhou, Yu; Shen, Zhihao; Fan, Xinghe; Ho, Rong-Ming.

Afiliación

Gu K; Beijing National Laboratory for Molecular Sciences, Key Laboratory of Polymer Chemistry and Physics of Ministry of Education, Center for Soft Matter Science and Engineering, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, China. zshen@pku.edu.cn.

Chem Commun (Camb) ; 53(86): 11794-11797, 2017 Aug 22.

Article en En | MEDLINE | ID: mdl-29034912

RESUMEN

Herein, we aim to demonstrate the shape effect of a giant molecule on the self-assembly of supramolecules. A bent-core (BC) molecule was covalently linked to a disc-like hexa-peri-hexabenzocoronene (HBC), giving a disc-bent core amphiphile. As a result, the induced hierarchical chirality driven by the shape effect on the forming columnar phase gives a two-dimensional nano-ribbon with spiral texture from double-stranded supracolumns.

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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Chem Commun (Camb) Asunto de la revista: QUIMICA Año: 2017 Tipo del documento: Article País de afiliación: China Pais de publicación: Reino Unido

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