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HPLC-MS/MS analysis of peramivir in rat plasma: Elimination of matrix effect using the phospholipid-removal solid-phase extraction method.
Lei, Mingdao; Gan, Wei; Sun, Yongbing.
Afiliación
  • Lei M; Department of Pharmacy, Jiangxi Maternal and Child Health Hospital, Nanchang, China.
  • Gan W; Division of Pharmaceutics, National Pharmaceutical Engineering Center for Solid Preparation in Chinese Herbal Medicine, Jiangxi University of Traditional Chinese Medicine, Nanchang, China.
  • Sun Y; Division of Pharmaceutics, National Pharmaceutical Engineering Center for Solid Preparation in Chinese Herbal Medicine, Jiangxi University of Traditional Chinese Medicine, Nanchang, China.
Biomed Chromatogr ; 32(3)2018 Mar.
Article en En | MEDLINE | ID: mdl-28976569
A simple HPLC-MS/MS method has been developed for the determination of peramivir in rat plasma in the present study. The analytes were separated on a C18 column (50 × 2.1 mm, 1.7 µm) and a triple-quadrupole mass spectrometer equipped with an electrospray ionization source was applied for the detection. A phospholipid-free cartridge solid-phase extraction was used to pretreat the plasma and eliminate the endogenous phospholipid. The in-source collision-induced dissociation approach showed that this pretreatment could result in negligible ion suppression from the extracted sample and could produce cleaner samples when compared with the protein precipitation. The method was linear over the concentration range of 0.12-1200.0 ng/mL for peramivir. The method was validated and successfully applied to a pharmacokinetic study after peramivir was orally and intravenously administered to Sprague-Dawley rats.
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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Asunto principal: Fosfolípidos / Cromatografía Líquida de Alta Presión / Ciclopentanos / Espectrometría de Masas en Tándem / Extracción en Fase Sólida / Guanidinas Tipo de estudio: Diagnostic_studies / Prognostic_studies Límite: Animals Idioma: En Revista: Biomed Chromatogr Año: 2018 Tipo del documento: Article País de afiliación: China Pais de publicación: Reino Unido

Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Asunto principal: Fosfolípidos / Cromatografía Líquida de Alta Presión / Ciclopentanos / Espectrometría de Masas en Tándem / Extracción en Fase Sólida / Guanidinas Tipo de estudio: Diagnostic_studies / Prognostic_studies Límite: Animals Idioma: En Revista: Biomed Chromatogr Año: 2018 Tipo del documento: Article País de afiliación: China Pais de publicación: Reino Unido