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A selective distance-based paper analytical device for copper(II) determination using a porphyrin derivative.
Pratiwi, Rimadani; Nguyen, Michael P; Ibrahim, Slamet; Yoshioka, Naoki; Henry, Charles S; Tjahjono, Daryono H.
Afiliación
  • Pratiwi R; School of Pharmacy, Institut Teknologi Bandung, Jalan Ganesha 10, Bandung 40132, Indonesia; Department of Pharmaceutical Analysis and Medicinal Chemistry, Faculty of Pharmacy, Universitas Padjadjaran, Jalan Raya Bandung-Sumedang KM 21, Jatinangor 45363, Indonesia; Department of Chemistry, Colorado S
  • Nguyen MP; Department of Chemistry, Colorado State University, Fort Collins, CO 80523, United States.
  • Ibrahim S; School of Pharmacy, Institut Teknologi Bandung, Jalan Ganesha 10, Bandung 40132, Indonesia.
  • Yoshioka N; Department of Applied Chemistry, Keio University, 3-14-1 Hiyoshi, Kohoku-ku, Yokohama 223-8522, Japan.
  • Henry CS; Department of Chemistry, Colorado State University, Fort Collins, CO 80523, United States. Electronic address: chuck.henry@colostate.edu.
  • Tjahjono DH; School of Pharmacy, Institut Teknologi Bandung, Jalan Ganesha 10, Bandung 40132, Indonesia. Electronic address: daryonohadi@fa.itb.ac.id.
Talanta ; 174: 493-499, 2017 Nov 01.
Article en En | MEDLINE | ID: mdl-28738613
Meso-tetrakis(1,2-dimethylpyrazolium-4-yl)porphyrin sulfonate (TDMPzP), a water-soluble porphyrin derivative, was synthesized and used as a colorimetric reagent for Cu2+ detection on a microfluidic paper-based analytical device (µPAD) using distance-based quantification. TDMPzP showed a high selectivity for Cu2+ detection in aqueous solutions. When Cu2+ was added to the TDMPzP under acidic conditions, a color change from green to a pink was observed by the naked eye. Under optimized conditions, the application of this system to a distance-based µPAD exhibited good analytical response. The presence of common metal ions (Al3+, Fe3+, Mg2+, Co2+, Mn2+, Zn2+, Pb2+, Cd2+, Sn2+, and Ni2+) did not interfere with Cu2+ detection within reasonable tolerance ratios. The lowest concentration of copper that could be measured was 1mgL-1 (1ppm) which meets the requirements for drinking water contamination regulations from the US Environmental Protection Agency (EPA) and World Health Organization (WHO) guidelines for drinking water. Real drinking water samples were analyzed to confirm the practical application of this system and the results showed good agreement with ICP-MS data. This distance-based µPAD based on TDMPzP for Cu2+ detection is convenient and effective for real-time drinking water analysis.
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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Asunto principal: Papel / Porfirinas / Colorimetría / Cobre / Dispositivos Laboratorio en un Chip Tipo de estudio: Guideline Idioma: En Revista: Talanta Año: 2017 Tipo del documento: Article Pais de publicación: Países Bajos
Texto completo
Añadir a Mi BVS
Imprimir
XML
PubMed Links
Buscar en Google

Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Asunto principal: Papel / Porfirinas / Colorimetría / Cobre / Dispositivos Laboratorio en un Chip Tipo de estudio: Guideline Idioma: En Revista: Talanta Año: 2017 Tipo del documento: Article Pais de publicación: Países Bajos