A family of 'windmill'-like {Cu<sub>6</sub>Ln<sub>12</sub>} complexes exhibiting single-molecule magnetism behavior and large magnetic entropy changes.

Alexandropoulos, Dimitris I; Poole, Katye M; Cunha-Silva, Luis; Ahmad Sheikh, Javeed; Wernsdorfer, Wolfgang; Christou, George; Stamatatos, Theocharis C

A family of 'windmill'-like {Cu₆Ln₁₂} complexes exhibiting single-molecule magnetism behavior and large magnetic entropy changes.

Alexandropoulos, Dimitris I; Poole, Katye M; Cunha-Silva, Luis; Ahmad Sheikh, Javeed; Wernsdorfer, Wolfgang; Christou, George; Stamatatos, Theocharis C.

Afiliación

Alexandropoulos DI; Department of Chemistry, Brock University, 1812 Sir Isaac Brock Way, L2S 3A1 St. Catharines, Ontario, Canada. tstamatatos@brocku.ca.

Chem Commun (Camb) ; 53(30): 4266-4269, 2017 Apr 11.

Article en En | MEDLINE | ID: mdl-28361136

RESUMEN

A family of nanosized {Cu6Ln12} clusters with a 'windmill'-like topology was prepared from the employment of 2,6-diacetylpyridine dioxime, in conjunction with bridging N3-, in 3d/4f-metal chemistry; the octadecanuclear compounds exhibit single-molecule magnetism behavior and large magnetic entropy changes, depending on the 4f-metal ion present.

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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Chem Commun (Camb) Asunto de la revista: QUIMICA Año: 2017 Tipo del documento: Article País de afiliación: Canadá Pais de publicación: Reino Unido

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