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Combination of amino acid/dipeptide with ligustrazine-betulinic acid as antitumor agents.
Xu, Bing; Yan, Wen-Qiang; Xu, Xin; Wu, Gao-Rong; Zhang, Chen-Ze; Han, Yao-Tian; Chu, Fu-Hao; Zhao, Rui; Wang, Peng-Long; Lei, Hai-Min.
Afiliación
  • Xu B; School of Chinese Pharmacy, Beijing University of Chinese Medicine, Beijing 100102, China.
  • Yan WQ; School of Chinese Pharmacy, Beijing University of Chinese Medicine, Beijing 100102, China.
  • Xu X; School of Chinese Pharmacy, Beijing University of Chinese Medicine, Beijing 100102, China.
  • Wu GR; School of Chinese Pharmacy, Beijing University of Chinese Medicine, Beijing 100102, China.
  • Zhang CZ; School of Chinese Pharmacy, Beijing University of Chinese Medicine, Beijing 100102, China.
  • Han YT; School of Chinese Pharmacy, Beijing University of Chinese Medicine, Beijing 100102, China.
  • Chu FH; School of Chinese Pharmacy, Beijing University of Chinese Medicine, Beijing 100102, China.
  • Zhao R; School of Chinese Pharmacy, Beijing University of Chinese Medicine, Beijing 100102, China.
  • Wang PL; School of Chinese Pharmacy, Beijing University of Chinese Medicine, Beijing 100102, China. Electronic address: wpl581@126.com.
  • Lei HM; School of Chinese Pharmacy, Beijing University of Chinese Medicine, Beijing 100102, China. Electronic address: hm_lei@126.com.
Eur J Med Chem ; 130: 26-38, 2017 Apr 21.
Article en En | MEDLINE | ID: mdl-28237794
The lead compound TBA, 3ß-Hydroxy-lup-20(29)-ene-28-oic acid-3, 5, 6-trimethylpyrazin-2-methyl ester, which exhibited promising antitumor activity and induced tumor cell apoptosis in various cancer cell lines, had previously been reported. Moreover, reports have revealed that the introduction of amino acid to betulinic acid could improve selective cytotoxicity as well as water solubility. Thus, a series of novel TBA amino acid and dipeptide derivatives were designed, synthesized and screened for selective cytotoxic activity against five cancer cell lines (HepG2, HT-29, Hela, BCG-823 and A549) and the not malignant cell line MDCK by standard MTT assay. Most of the tested TBA-amino acid and dipeptide analogues showed stronger anti-proliferative activity against all tested tumor cell lines than TBA. Among them, BA-25 exhibited the greatest cytotoxic activity on tumor cell lines (mean IC50 = 2.31 ± 0.78 µM), that was twofold than the positive drug cisplatin (DDP), while it showed lower cytotoxicity on MDCK cell line than DDP. Further cell apoptosis analyses indicated BA-25-induced apoptosis was associated with loss of mitochondrial membrane potential and increase of intracellular free Ca2+ concentration.
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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Asunto principal: Pirazinas / Triterpenos / Aminoácidos / Antineoplásicos Límite: Humans Idioma: En Revista: Eur J Med Chem Año: 2017 Tipo del documento: Article País de afiliación: China Pais de publicación: Francia

Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Asunto principal: Pirazinas / Triterpenos / Aminoácidos / Antineoplásicos Límite: Humans Idioma: En Revista: Eur J Med Chem Año: 2017 Tipo del documento: Article País de afiliación: China Pais de publicación: Francia