Nickel-catalyzed product-controllable amidation and imidation of sp<sup>3</sup> C-H bonds in substituted toluenes with sulfonamides.

Li, Ze-Lin; Jin, Li-Kun; Cai, Chun

Nickel-catalyzed product-controllable amidation and imidation of sp³ C-H bonds in substituted toluenes with sulfonamides.

Li, Ze-Lin; Jin, Li-Kun; Cai, Chun.

Afiliación

Li ZL; Chemical Engineering College, Nanjing University of Science and Technology, 200 Xiao Ling Wei Street, Nanjing, Jiangsu, People's Republic of China. c.cai@njust.edu.cn.
Jin LK; Chemical Engineering College, Nanjing University of Science and Technology, 200 Xiao Ling Wei Street, Nanjing, Jiangsu, People's Republic of China. c.cai@njust.edu.cn.
Cai C; Chemical Engineering College, Nanjing University of Science and Technology, 200 Xiao Ling Wei Street, Nanjing, Jiangsu, People's Republic of China. c.cai@njust.edu.cn.

Org Biomol Chem ; 15(6): 1317-1320, 2017 Feb 07.

Article en En | MEDLINE | ID: mdl-28102418

RESUMEN

A nickel-catalyzed product-controllable imidation and amidation of sp3 C-H bonds in substituted toluenes with sulfonamides were developed. Based on the change of the reaction time and atmosphere from N2 to O2, this reaction proceeded in high yields and excellent selectivity under different conditions. Mechanistic details were also described.

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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Org Biomol Chem Asunto de la revista: BIOQUIMICA / QUIMICA Año: 2017 Tipo del documento: Article Pais de publicación: Reino Unido

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