Gold(III) Triggered Transformations of 22-Methyl-m-benziporphyrin Involving an Effective Contraction of Benzene to Cyclopentadiene.

Hurej, Karolina; Pawlicki, Milosz; Latos-Grazynski, Lechoslaw

Hurej, Karolina; Pawlicki, Milosz; Latos-Grazynski, Lechoslaw.

Afiliación

Hurej K; Department of Chemistry, University of Wroclaw, ul.14âF. Joliot-Curie, 50-383, Wroclaw, Poland.
Pawlicki M; Department of Chemistry, University of Wroclaw, ul.14âF. Joliot-Curie, 50-383, Wroclaw, Poland.
Latos-Grazynski L; Department of Chemistry, University of Wroclaw, ul.14âF. Joliot-Curie, 50-383, Wroclaw, Poland.

Chemistry ; 23(9): 2059-2066, 2017 Feb 10.

Article en En | MEDLINE | ID: mdl-27981629

RESUMEN

A structurally prearranged carbaporphyrin, 22-methyl-m-benziporphyrin, provided the perfect macrocyclic platform to form gold(III) 22-methyl-m-benziporphyrin, which facilitates the specific m-benzene ring contraction yielding gold(III) 21-methyl 21-carbaporphyrin with remarkably high yield.

Palabras clave

benzene; carbaporphyrinoid; contraction; gold; porphyrin

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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Chemistry Asunto de la revista: QUIMICA Año: 2017 Tipo del documento: Article País de afiliación: Polonia Pais de publicación: Alemania

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