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Combining contamination indexes, sediment quality guidelines and multivariate data analysis for metal pollution assessment in marine sediments of Cienfuegos Bay, Cuba.
Peña-Icart, Mirella; Pereira-Filho, Edenir Rodrigues; Lopes Fialho, Lucimar; Nóbrega, Joaquim A; Alonso-Hernández, Carlos; Bolaños-Alvarez, Yoelvis; Pomares-Alfonso, Mario S.
Afiliación
  • Peña-Icart M; Institute of Materials Science and Technology (IMRE), University of Havana, CP 10400 Havana, Cuba; Grupo de Análise Instrumental Aplicada (GAIA), Departamento de Química (DQ), Universidade Federal de São Carlos (UFSCar), PO Box 676, 13565-905 São Carlos, SP, Brazil.
  • Pereira-Filho ER; Grupo de Análise Instrumental Aplicada (GAIA), Departamento de Química (DQ), Universidade Federal de São Carlos (UFSCar), PO Box 676, 13565-905 São Carlos, SP, Brazil.
  • Lopes Fialho L; Grupo de Análise Instrumental Aplicada (GAIA), Departamento de Química (DQ), Universidade Federal de São Carlos (UFSCar), PO Box 676, 13565-905 São Carlos, SP, Brazil.
  • Nóbrega JA; Grupo de Análise Instrumental Aplicada (GAIA), Departamento de Química (DQ), Universidade Federal de São Carlos (UFSCar), PO Box 676, 13565-905 São Carlos, SP, Brazil.
  • Alonso-Hernández C; Cienfuegos City Environmental Study Center, St. Castillo de Jagua, km 1 ½, A.P. 5, CP 59350 Cienfuegos City, Cuba.
  • Bolaños-Alvarez Y; Cienfuegos City Environmental Study Center, St. Castillo de Jagua, km 1 ½, A.P. 5, CP 59350 Cienfuegos City, Cuba.
  • Pomares-Alfonso MS; Institute of Materials Science and Technology (IMRE), University of Havana, CP 10400 Havana, Cuba. Electronic address: mpomares@imre.oc.uh.cu.
Chemosphere ; 168: 1267-1276, 2017 Feb.
Article en En | MEDLINE | ID: mdl-27823778
The purpose of the present work was to combine several tools for assessing metal pollution in marine sediments from Cienfuegos Bay. Fourteen surface sediments collected in 2013 were evaluated. Concentrations of As, Cu, Ni, Zn and V decreased respect to those previous reported. The metal contamination was spatially distributed in the north and south parts of the bay. According to the contamination factor (CF) enrichment factor (EF) and index of geoaccumulation (Igeo), Cd and Cu were classified in that order as the most contaminated elements in most sediment. Comparison of the total metal concentrations with the threshold (TELs) and probable (PELs) effect levels in sediment quality guidelines suggested a more worrisome situation for Cu, of which concentrations were occasional associated with adverse biological effects in thirteen sediments, followed by Ni in nine sediments; while adverse effects were rarely associated with Cd. Probably, Cu could be considered as the most dangerous in the whole bay because it was classified in the high contamination levels by all indexes and, simultaneously, associated to occasional adverse effects in most samples. Despite the bioavailability was partially evaluated with the HCl method, the low extraction of Ni (<3% in all samples) and Cu (<55%, except sample 3) and the relative high extraction of Cd (50% or more, except sample 14) could be considered as an attenuating (Ni and Cu) or increasing (Cd) factor in the risk assessment of those element.
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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Asunto principal: Arsénico / Contaminantes Químicos del Agua / Contaminación Química del Agua / Metales Pesados Tipo de estudio: Guideline / Risk_factors_studies País/Región como asunto: Caribe / Cuba Idioma: En Revista: Chemosphere Año: 2017 Tipo del documento: Article País de afiliación: Brasil Pais de publicación: Reino Unido

Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Asunto principal: Arsénico / Contaminantes Químicos del Agua / Contaminación Química del Agua / Metales Pesados Tipo de estudio: Guideline / Risk_factors_studies País/Región como asunto: Caribe / Cuba Idioma: En Revista: Chemosphere Año: 2017 Tipo del documento: Article País de afiliación: Brasil Pais de publicación: Reino Unido