Reactivity, vibrational spectroscopy, internal rotation and thermochemical aspects of methylarsine.
Spectrochim Acta A Mol Biomol Spectrosc
; 171: 383-394, 2017 Jan 15.
Article
en En
| MEDLINE
| ID: mdl-27569771
The aim of this investigation was to perform a characterization of the spectroscopic and thermodynamic properties of methylarsine (CH3AsH2). Post-Hartree-Fock, 29 DFT methods and eight different composite methodologies were employed in these analyses. A comparison between harmonic and anharmonic frequency accuracies in reproducing the observable frequencies was performed here. In addition, the CH3AsH2âCH2AsH3 isomerization barrier energy was estimated in 100kcalmol-1, whereas the H2-release routes barrier heights were in the 45-107kcalmol-1 range. A rate constant of 10-66s-1 was predicted regarding the isomerization route, while the CH2AsH3 hydrogen elimination mechanism is faster than the methylarsine one. The transition state structure of the CH3AsH2 internal rotational barrier energy varied between 1.0 and 1.4kcalmol-1. For the CH2AsH3 internal rotation the estimated barrier heights varied 0.6-2.5kcalmol-1. The adiabatic ionization energy and the heat of formation each structure was also calculated here.
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1
Colección:
01-internacional
Base de datos:
MEDLINE
Idioma:
En
Revista:
Spectrochim Acta A Mol Biomol Spectrosc
Asunto de la revista:
BIOLOGIA MOLECULAR
Año:
2017
Tipo del documento:
Article
Pais de publicación:
Reino Unido