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Nickel-catalyzed C-N bond reduction of aromatic and benzylic quaternary ammonium triflates.
Yi, Yuan-Qiu-Qiang; Yang, Wen-Cheng; Zhai, Dan-Dan; Zhang, Xiang-Yu; Li, Shuai-Qi; Guan, Bing-Tao.
Afiliación
  • Yi YQ; State Key Laboratory and Institute of Elemento-Organic Chemistry, Collaborative Innovation Center of Chemical Science and Engineering, Nankai University, Tianjin, 300071, China. guan@nankai.edu.cn.
Chem Commun (Camb) ; 52(72): 10894-7, 2016 Sep 18.
Article en En | MEDLINE | ID: mdl-27530274
A nickel-catalyzed, efficient C-N bond reduction of aromatic and benzylic ammonium triflates has been developed using sodium isopropoxide as a reducing agent. The high efficiency, mild conditions, and good compatibility with various substituents made this method an effective supplement to the current catalytic hydrogenation reactions. Combining this reductive deamination reaction with directed aromatic functionalization reactions, a powerful strategy for regioselective functionalization of arenes was demonstrated using dialkylamine groups as traceless directing groups.
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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Chem Commun (Camb) Asunto de la revista: QUIMICA Año: 2016 Tipo del documento: Article País de afiliación: China Pais de publicación: Reino Unido
Texto completo
Añadir a Mi BVS
Imprimir
XML
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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Chem Commun (Camb) Asunto de la revista: QUIMICA Año: 2016 Tipo del documento: Article País de afiliación: China Pais de publicación: Reino Unido