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Fullerene Derivatives Strongly Inhibit HIV-1 Replication by Affecting Virus Maturation without Impairing Protease Activity.
Martinez, Zachary S; Castro, Edison; Seong, Chang-Soo; Cerón, Maira R; Echegoyen, Luis; Llano, Manuel.
Afiliación
  • Martinez ZS; Department of Biological Sciences, University of Texas at El Paso, El Paso, Texas, USA.
  • Castro E; Department of Chemistry, University of Texas at El Paso, El Paso, Texas, USA.
  • Seong CS; Department of Biological Sciences, University of Texas at El Paso, El Paso, Texas, USA.
  • Cerón MR; Department of Chemistry, University of Texas at El Paso, El Paso, Texas, USA.
  • Echegoyen L; Department of Chemistry, University of Texas at El Paso, El Paso, Texas, USA echegoyen@utep.edu mllano@utep.edu.
  • Llano M; Department of Biological Sciences, University of Texas at El Paso, El Paso, Texas, USA echegoyen@utep.edu mllano@utep.edu.
Antimicrob Agents Chemother ; 60(10): 5731-41, 2016 10.
Article en En | MEDLINE | ID: mdl-27431232
Three compounds (1, 2, and 3) previously reported to inhibit HIV-1 replication and/or in vitro activity of reverse transcriptase were studied, but only fullerene derivatives 1 and 2 showed strong antiviral activity on the replication of HIV-1 in human CD4(+) T cells. However, these compounds did not inhibit infection by single-round infection vesicular stomatitis virus glycoprotein G (VSV-G)-pseudotyped viruses, indicating no effect on the early steps of the viral life cycle. In contrast, analysis of single-round infection VSV-G-pseudotyped HIV-1 produced in the presence of compound 1 or 2 showed a complete lack of infectivity in human CD4(+) T cells, suggesting that the late stages of the HIV-1 life cycle were affected. Quantification of virion-associated viral RNA and p24 indicates that RNA packaging and viral production were unremarkable in these viruses. However, Gag and Gag-Pol processing was affected, as evidenced by immunoblot analysis with an anti-p24 antibody and the measurement of virion-associated reverse transcriptase activity, ratifying the effect of the fullerene derivatives on virion maturation of the HIV-1 life cycle. Surprisingly, fullerenes 1 and 2 did not inhibit HIV-1 protease in an in vitro assay at the doses that potently blocked viral infectivity, suggesting a protease-independent mechanism of action. Highlighting the potential therapeutic relevance of fullerene derivatives, these compounds block infection by HIV-1 resistant to protease and maturation inhibitors.
Asunto(s)

Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Asunto principal: VIH-1 / Fármacos Anti-VIH / Fulerenos Límite: Humans Idioma: En Revista: Antimicrob Agents Chemother Año: 2016 Tipo del documento: Article País de afiliación: Estados Unidos Pais de publicación: Estados Unidos

Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Asunto principal: VIH-1 / Fármacos Anti-VIH / Fulerenos Límite: Humans Idioma: En Revista: Antimicrob Agents Chemother Año: 2016 Tipo del documento: Article País de afiliación: Estados Unidos Pais de publicación: Estados Unidos