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Temporal and Triggered Evolution of Host-Guest Characteristics in Amphiphilic Polymer Assemblies.
Rangadurai, Poornima; Molla, Mijanur Rahaman; Prasad, Priyaa; Caissy, Matthew; Thayumanavan, S.
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  • Rangadurai P; Department of Chemistry, University of Massachusetts , 710 N. Pleasant Street, Amherst, Massachusetts 01003-9336, United States.
  • Molla MR; Department of Chemistry, University of Massachusetts , 710 N. Pleasant Street, Amherst, Massachusetts 01003-9336, United States.
  • Prasad P; Department of Chemistry, University of Massachusetts , 710 N. Pleasant Street, Amherst, Massachusetts 01003-9336, United States.
  • Caissy M; Department of Chemistry, University of Massachusetts , 710 N. Pleasant Street, Amherst, Massachusetts 01003-9336, United States.
  • Thayumanavan S; Department of Chemistry, University of Massachusetts , 710 N. Pleasant Street, Amherst, Massachusetts 01003-9336, United States.
J Am Chem Soc ; 138(24): 7508-11, 2016 06 22.
Article en En | MEDLINE | ID: mdl-27258854
An amphiphilic polymer with cleavable side chain and main chain functional groups has been designed and synthesized. Specific cleavage of either of its functional groups was found to have an effect on the morphology of the assembly. Degradation of the main chain is shown to cause morphology of the supramolecular assembly to evolve with time from a micelle-like assembly to a vesicular assembly. On the other hand, stimulus-induced cleavage of the side chains causes these nanoassemblies to disassemble. These temporal (main chain) and triggered (side chain) degradation processes have implications in the design of degradable polymers as supramolecular scaffolds for biological applications.
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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Asunto principal: Polímeros / Tensoactivos Idioma: En Revista: J Am Chem Soc Año: 2016 Tipo del documento: Article País de afiliación: Estados Unidos Pais de publicación: Estados Unidos
Texto completo
Añadir a Mi BVS
Imprimir
XML
PubMed Links
Buscar en Google

Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Asunto principal: Polímeros / Tensoactivos Idioma: En Revista: J Am Chem Soc Año: 2016 Tipo del documento: Article País de afiliación: Estados Unidos Pais de publicación: Estados Unidos