Novel Convenient Synthesis of (10)B-Enriched Sodium Borohydride.

Safronov, Alexander V; Jalisatgi, Satish S; Hawthorne, M Frederick

Safronov, Alexander V; Jalisatgi, Satish S; Hawthorne, M Frederick.

Afiliación

Safronov AV; International Institute of Nano and Molecular Medicine, School of Medicine, University of Missouri-Columbia , 1514 Research Park Drive, Columbia, Missouri 65211, United States.
Jalisatgi SS; International Institute of Nano and Molecular Medicine, School of Medicine, University of Missouri-Columbia , 1514 Research Park Drive, Columbia, Missouri 65211, United States.
Hawthorne MF; International Institute of Nano and Molecular Medicine, School of Medicine, University of Missouri-Columbia , 1514 Research Park Drive, Columbia, Missouri 65211, United States.

Inorg Chem ; 55(11): 5116-7, 2016 06 06.

Article en En | MEDLINE | ID: mdl-27195803

RESUMEN

A convenient and efficient synthesis of (10)B-enriched sodium borohydride [Na(10)BH4] from commercially available (10)B-enriched boric acid [(10)B(OH)3] is described. The reaction sequence (10)B(OH)3 â (10)B(On-Bu)3 â (10)BH3·Et3N â Na(10)BH4 afforded the product in 60-80% yield. The reaction was successfully scaled to hundreds of gram per run.

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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Inorg Chem Año: 2016 Tipo del documento: Article País de afiliación: Estados Unidos Pais de publicación: Estados Unidos

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