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Ordered Layered Dendrimers Constructed from Two Known Dendrimer Families: Inheritance and Emergence of Properties.
Dib, Hanna; Rebout, Cyrille; Laurent, Régis; Mallet-Ladeira, Sonia; Sournia-Saquet, Alix; Sárosi, Menyhárt B; Hey-Hawkins, Evamarie; Majoral, Jean-Pierre; Delavaux-Nicot, Béatrice; Caminade, Anne-Marie.
Afiliación
  • Dib H; Laboratoire de Chimie de Coordination, CNRS, 205 Route de Narbonne, BP 44099, 31077, Toulouse Cedex 4, France.
  • Rebout C; Université de Toulouse, UPS, INPT, 31077, Toulouse Cedex 4, France.
  • Laurent R; Laboratoire de Chimie de Coordination, CNRS, 205 Route de Narbonne, BP 44099, 31077, Toulouse Cedex 4, France.
  • Mallet-Ladeira S; Université de Toulouse, UPS, INPT, 31077, Toulouse Cedex 4, France.
  • Sournia-Saquet A; Laboratoire de Chimie de Coordination, CNRS, 205 Route de Narbonne, BP 44099, 31077, Toulouse Cedex 4, France.
  • Sárosi MB; Université de Toulouse, UPS, INPT, 31077, Toulouse Cedex 4, France.
  • Hey-Hawkins E; Laboratoire de Chimie de Coordination, CNRS, 205 Route de Narbonne, BP 44099, 31077, Toulouse Cedex 4, France.
  • Majoral JP; Université de Toulouse, UPS, INPT, 31077, Toulouse Cedex 4, France.
  • Delavaux-Nicot B; Laboratoire de Chimie de Coordination, CNRS, 205 Route de Narbonne, BP 44099, 31077, Toulouse Cedex 4, France.
  • Caminade AM; Université de Toulouse, UPS, INPT, 31077, Toulouse Cedex 4, France.
Chemistry ; 22(31): 10736-42, 2016 Jul 25.
Article en En | MEDLINE | ID: mdl-27140418
A new concept is presented, namely the synthesis of dendrimers intrinsically composed in alternation of building blocks pertaining to two known families of dendrimers: phosphorhydrazone dendrimers and triazine-piperazine dendrimers. These mixed dendrimers with layered controlled architecture inherit their easy (31) P NMR characterization and their thermal stability from the phosphorhydrazone family, and their decreased solubility from the triazine-piperazine family. However, they have also their own and original characteristics. Both parent families are white powders, whereas the mixed dendrimers are yellow, orange, or red powders, depending on the generation. DFT calculations were carried out on model dendrons to understand these special color features. Remarkably, these dendrimers incorporating redox-active organic entities allow for the first time the monitoring of the growth of an organic dendrimer by electrochemistry while highlighting an even-odd generation behavior.
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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Tipo de estudio: Prognostic_studies Idioma: En Revista: Chemistry Asunto de la revista: QUIMICA Año: 2016 Tipo del documento: Article País de afiliación: Francia Pais de publicación: Alemania
Texto completo
Añadir a Mi BVS
Imprimir
XML
PubMed Links
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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Tipo de estudio: Prognostic_studies Idioma: En Revista: Chemistry Asunto de la revista: QUIMICA Año: 2016 Tipo del documento: Article País de afiliación: Francia Pais de publicación: Alemania