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BODIPY atropisomer interconversion, face discrimination, and superstructure appending.
Doulain, Pierre-Emmanuel; Goze, Christine; Bodio, Ewen; Richard, Philippe; Decréau, Richard A.
Afiliación
  • Doulain PE; ICMUB Institute - Department of Chemistry, University of Burgundy - Franche Comté, 9, Avenue Alain Savary, 21078 Dijon, France. Richard.Decreau@u-bourgogne.fr.
  • Goze C; ICMUB Institute - Department of Chemistry, University of Burgundy - Franche Comté, 9, Avenue Alain Savary, 21078 Dijon, France. Richard.Decreau@u-bourgogne.fr.
  • Bodio E; ICMUB Institute - Department of Chemistry, University of Burgundy - Franche Comté, 9, Avenue Alain Savary, 21078 Dijon, France. Richard.Decreau@u-bourgogne.fr.
  • Richard P; ICMUB Institute - Department of Chemistry, University of Burgundy - Franche Comté, 9, Avenue Alain Savary, 21078 Dijon, France. Richard.Decreau@u-bourgogne.fr.
  • Decréau RA; ICMUB Institute - Department of Chemistry, University of Burgundy - Franche Comté, 9, Avenue Alain Savary, 21078 Dijon, France. Richard.Decreau@u-bourgogne.fr.
Chem Commun (Camb) ; 52(24): 4474-7, 2016 Mar 25.
Article en En | MEDLINE | ID: mdl-26927530
A strategy was developed to append sterically hindered apical pickets on both faces of the BODIPY platform to prevent stacking and aggregation. Ortho-substitution of both the meso-phenyl ring and the boron-bound catechol affords the right directionality to append pickets, achieve face discrimination, featuring two interconvertible atropisomers, and is reminiscent of the picket-fence strategy in porphyrins.

Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Tipo de estudio: Prognostic_studies Idioma: En Revista: Chem Commun (Camb) Asunto de la revista: QUIMICA Año: 2016 Tipo del documento: Article País de afiliación: Francia Pais de publicación: Reino Unido

Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Tipo de estudio: Prognostic_studies Idioma: En Revista: Chem Commun (Camb) Asunto de la revista: QUIMICA Año: 2016 Tipo del documento: Article País de afiliación: Francia Pais de publicación: Reino Unido