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Decacyclene Trianhydride at Functional Interfaces: An Ideal Electron Acceptor Material for Organic Electronics.
de Oteyza, Dimas G; Garcia-Lastra, Juan M; Toma, Francesca M; Borghetti, Patrizia; Floreano, Luca; Verdini, Alberto; Cossaro, Albano; Pho, Toan V; Wudl, Fred; Ortega, J Enrique.
Afiliación
  • de Oteyza DG; Donostia International Physics Center, Paseo Manuel Lardizabal 4 , 20018 San Sebastián, Spain.
  • Garcia-Lastra JM; Centro de Física de Materiales (CSIC-UPV/EHU) - Materials Physics Center (MPC), Paseo Manuel Lardizabal 5, 20018 San Sebastián, Spain.
  • Toma FM; Ikerbasque, Basque Foundation for Science, 48011 Bilbao, Spain.
  • Borghetti P; Department of Energy Conversion and Storage, Technical University of Denmark , DK-4000 Roskilde, Denmark.
  • Floreano L; Department of Chemistry and Biochemistry, Department of Materials, Center for Polymers and Organic Solids, University of California , Santa Barbara, California 93106, United States.
  • Verdini A; Chemical Sciences Division, Lawrence Berkeley National Laboratory , Berkeley, California 94720, United States.
  • Cossaro A; Donostia International Physics Center, Paseo Manuel Lardizabal 4 , 20018 San Sebastián, Spain.
  • Pho TV; CNR-IOM, Laboratorio Nazionale TASC, Basovizza SS-14 Km. 163.5, Trieste 34149, Italy.
  • Wudl F; CNR-IOM, Laboratorio Nazionale TASC, Basovizza SS-14 Km. 163.5, Trieste 34149, Italy.
  • Ortega JE; CNR-IOM, Laboratorio Nazionale TASC, Basovizza SS-14 Km. 163.5, Trieste 34149, Italy.
J Phys Chem Lett ; 7(1): 90-5, 2016 Jan 07.
Article en En | MEDLINE | ID: mdl-26651535
We report the interface energetics of decacyclene trianhydride (DTA) monolayers on top of two distinct model surfaces, namely, Au(111) and Ag(111). On the latter, combined valence band photoemission and X-ray absorption measurements that access the occupied and unoccupied molecular orbitals, respectively, reveal that electron transfer from substrate to surface sets in. Density functional theory calculations confirm our experimental findings and provide an understanding not only of the photoemission and X-ray absorption spectral features of this promising organic semiconductor but also of the fingerprints associated with the interface charge transfer.
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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Tipo de estudio: Prognostic_studies Idioma: En Revista: J Phys Chem Lett Año: 2016 Tipo del documento: Article País de afiliación: España Pais de publicación: Estados Unidos

Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Tipo de estudio: Prognostic_studies Idioma: En Revista: J Phys Chem Lett Año: 2016 Tipo del documento: Article País de afiliación: España Pais de publicación: Estados Unidos