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Zinc(II)-Mediated Carbene Insertion into C-H Bonds in Alkanes.
Kulkarni, Naveen V; Dash, Chandrakanta; Jayaratna, Naleen B; Ridlen, Shawn G; Karbalaei Khani, Sarah; Das, Animesh; Kou, Xiaodi; Yousufuddin, Muhammed; Cundari, Thomas R; Dias, H V Rasika.
Afiliación
  • Kulkarni NV; Department of Chemistry and Biochemistry, The University of Texas at Arlington , Arlington, Texas 76019, United States.
  • Dash C; Department of Chemistry and Biochemistry, The University of Texas at Arlington , Arlington, Texas 76019, United States.
  • Jayaratna NB; Department of Chemistry and Biochemistry, The University of Texas at Arlington , Arlington, Texas 76019, United States.
  • Ridlen SG; Department of Chemistry and Biochemistry, The University of Texas at Arlington , Arlington, Texas 76019, United States.
  • Karbalaei Khani S; Department of Chemistry, Center for Advanced Scientific Computing and Modeling, University of North Texas , Denton, Texas 76203, United States.
  • Das A; Department of Chemistry and Biochemistry, The University of Texas at Arlington , Arlington, Texas 76019, United States.
  • Kou X; Department of Chemistry and Biochemistry, The University of Texas at Arlington , Arlington, Texas 76019, United States.
  • Yousufuddin M; Department of Chemistry and Biochemistry, The University of Texas at Arlington , Arlington, Texas 76019, United States.
  • Cundari TR; Department of Chemistry, Center for Advanced Scientific Computing and Modeling, University of North Texas , Denton, Texas 76203, United States.
  • Dias HV; Department of Chemistry and Biochemistry, The University of Texas at Arlington , Arlington, Texas 76019, United States.
Inorg Chem ; 54(23): 11043-5, 2015 Dec 07.
Article en En | MEDLINE | ID: mdl-26587680
The cationic zinc adduct {[HB(3,5-(CF3)2Pz)3]Zn(NCMe)2}ClO4 catalyzes the functionalization of tertiary, secondary, and primary C-H bonds of alkanes via carbene insertion. Ethyl diazoacetate serves as the :CHCO2Et carbene precursor. The counteranion, supporting ligand, and coordinating solvents affect the catalytic activity. An in situ generated {[HB(3,5-(CF3)2Pz)3]Zn}(+) species containing a bulkier {B[3,5-(CF3)2C6H3]4}(-) anion gives the best results among the zinc catalysts used.
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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Inorg Chem Año: 2015 Tipo del documento: Article País de afiliación: Estados Unidos Pais de publicación: Estados Unidos
Texto completo
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XML
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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Inorg Chem Año: 2015 Tipo del documento: Article País de afiliación: Estados Unidos Pais de publicación: Estados Unidos