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Characterization of antiproliferative potential and biological targets of a copper compound containing 4'-phenyl terpyridine.
Mendo, Ana Soraia; Figueiredo, Sara; Roma-Rodrigues, Catarina; Videira, Paula A; Ma, Zhen; Diniz, Mário; Larguinho, Miguel; Costa, Pedro M; Lima, João C; Pombeiro, Armando J L; Baptista, Pedro V; Fernandes, Alexandra R.
Afiliación
  • Mendo AS; Departamento de Ciências da Vida, UCIBIO, Faculdade de Ciências e Tecnologia da Universidade Nova de Lisboa, Campus de Caparica, 2829-516, Caparica, Portugal.
J Biol Inorg Chem ; 20(6): 935-48, 2015 Sep.
Article en En | MEDLINE | ID: mdl-26077814
Several copper complexes have been assessed as anti-tumor agents against cancer cells. In this work, a copper compound [Cu(H2O){OS(CH3)2}L](NO3)2 incorporating the ligand 4'-phenyl-terpyridine antiproliferative activity against human colorectal, hepatocellular carcinomas and breast adenocarcinoma cell lines was determined, demonstrating high cytotoxicity. The compound is able to induce apoptosis and a slight delay in cancer cell cycle progression, probably by its interaction with DNA and induction of double-strand pDNA cleavage, which is enhanced by oxidative mechanisms. Moreover, proteomic studies indicate that the compound induces alterations in proteins involved in cytoskeleton maintenance, cell cycle progression and apoptosis, corroborating its antiproliferative potential.
Asunto(s)

Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Asunto principal: Piridinas / Cobre / Complejos de Coordinación / Antineoplásicos Límite: Humans Idioma: En Revista: J Biol Inorg Chem Asunto de la revista: BIOQUIMICA Año: 2015 Tipo del documento: Article País de afiliación: Portugal Pais de publicación: Alemania

Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Asunto principal: Piridinas / Cobre / Complejos de Coordinación / Antineoplásicos Límite: Humans Idioma: En Revista: J Biol Inorg Chem Asunto de la revista: BIOQUIMICA Año: 2015 Tipo del documento: Article País de afiliación: Portugal Pais de publicación: Alemania