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Transformation of hydrogen titanate nanoribbons to TiO2 nanoribbons and the influence of the transformation strategies on the photocatalytic performance.
Rutar, Melita; Rozman, Nejc; Pregelj, Matej; Bittencourt, Carla; Cerc Korosec, Romana; Sever Skapin, Andrijana; Mrzel, Ales; Skapin, Sreco D; Umek, Polona.
Afiliación
  • Rutar M; Jozef Stefan Institute, Jamova cesta 39, SI-1000 Ljubljana, Slovenia ; Jozef Stefan International Postgraduate School, Jamova cesta 39, SI-1000 Ljubljana, SIovenia.
  • Rozman N; Slovenian National Building and Civil Engineering Institute, Dimiceva 12, SI-1000 Ljubljana, Slovenia.
  • Pregelj M; Jozef Stefan Institute, Jamova cesta 39, SI-1000 Ljubljana, Slovenia.
  • Bittencourt C; Chimie des Interactions Plasma Surface, CIRMAP, University of Mons, 23 Place du Parc, B-7000 Mons, Belgium.
  • Cerc Korosec R; Faculty of Chemistry and Chemical Technology, University of Ljubljana, Askerceva cesta 5, SI-1000 Ljubljana, Slovenia.
  • Sever Skapin A; Slovenian National Building and Civil Engineering Institute, Dimiceva 12, SI-1000 Ljubljana, Slovenia.
  • Mrzel A; Jozef Stefan Institute, Jamova cesta 39, SI-1000 Ljubljana, Slovenia.
  • Skapin SD; Jozef Stefan Institute, Jamova cesta 39, SI-1000 Ljubljana, Slovenia.
  • Umek P; Jozef Stefan Institute, Jamova cesta 39, SI-1000 Ljubljana, Slovenia.
Beilstein J Nanotechnol ; 6: 831-44, 2015.
Article en En | MEDLINE | ID: mdl-25977854
The influence of the reaction conditions during the transformation of hydrogen titanate nanoribbons to TiO2 nanoribbons on the phase composition, the morphology, the appearance of the nanoribbon surfaces and their optical properties was investigated. The transformations were performed (i) through a heat treatment in oxidative and reductive atmospheres in the temperature range of 400-650 °C, (ii) through a hydrothermal treatment in neutral and basic environments at 160 °C, and (iii) through a microwave-assisted hydrothermal treatment in a neutral environment at 200 °C. Scanning electron microscopy investigations showed that the hydrothermal processing significantly affected the nanoribbon surfaces, which became rougher, while the transformations based on calcination in either oxidative or reductive atmospheres had no effect on the morphology or on the surface appearance of the nanoribbons. The transformations performed in the reductive atmosphere, an NH3(g)/Ar(g) flow, and in the ammonia solution led to nitrogen doping. The nitrogen content increased with an increasing calcination temperature, as was determined by X-ray photoelectron spectroscopy. According to electron paramagnetic resonance measurements the calcination in the reductive atmosphere also resulted in a partial reduction of Ti(4+) to Ti(3+). The photocatalytic performance of the derived TiO2 NRs was estimated on the basis of the photocatalytic oxidation of isopropanol. After calcinating in air, the photocatalytic performance of the investigated TiO2 NRs increased with an increased content of anatase. In contrast, the photocatalytic performance of the N-doped TiO2 NRs showed no dependence on the calcination temperature. An additional comparison showed that the N-doping significantly suppressed the photocatalytic performance of the TiO2 NRs, i.e., by 3 to almost 10 times, in comparison with the TiO2 NRs derived by calcination in air. On the other hand, the photocatalytic performance of the hydrothermally derived TiO2 NRs was additionally improved by a subsequent heat treatment in air.
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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Beilstein J Nanotechnol Año: 2015 Tipo del documento: Article Pais de publicación: Alemania

Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Beilstein J Nanotechnol Año: 2015 Tipo del documento: Article Pais de publicación: Alemania