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Rapid quantification of 2-hydroxypropyl-ß-cyclodextrin in liquid pharmaceutical formulations by (1)H nuclear magnetic resonance spectroscopy.
Dufour, Gilles; Evrard, Brigitte; de Tullio, Pascal.
Afiliación
  • Dufour G; Laboratory of Pharmaceutical Technology and Biopharmacy, Department of Pharmacy, Centre Interfacultaire de Recherche du Médicament (CIRM), University of Liege, 4000 Liège, Belgium. Electronic address: gilles.dufour@ulg.ac.be.
  • Evrard B; Laboratory of Pharmaceutical Technology and Biopharmacy, Department of Pharmacy, Centre Interfacultaire de Recherche du Médicament (CIRM), University of Liege, 4000 Liège, Belgium.
  • de Tullio P; Laboratory of Medicinal Chemistry, Department of Pharmacy, Centre Interfacultaire de Recherche du Médicament (CIRM), University of Liege, 4000 Liège, Belgium.
Eur J Pharm Sci ; 73: 20-8, 2015 Jun 20.
Article en En | MEDLINE | ID: mdl-25797290
Quantification of 2-hydroxypropyl-ß-cyclodextrin (2-HP-ß-CD) is not yet described in United States Pharmacopeia (USP) and European Pharmacopeia (EP). A useful quality control tool is therefore needed for the specific quantification in finished liquid pharmaceutical products, especially for formulations containing 2-HP-ß-CD as an active ingredient. A new technique is also mandatory for the development of future formulations in which 2-HP-ß-CD concentration could influence the properties of these formulations. Here, we described the use of (1)H NMR for the rapid quantification of 2-HP-ß-CD directly into pharmaceutical solutions without any extraction or separation steps. This technique was successfully applied to different pharmaceutical solutions comprising an i.v. solution (budesonide/2-HP-ß-CD complex), an eye drop solution (Indocollyre®) and an oral solution (Sporanox®). Specificity, linearity, precision (repeatability and intermediate precision), trueness, limits of quantification (LOQs) and accuracy were used as validation criteria.
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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Asunto principal: Beta-Ciclodextrinas / Excipientes Idioma: En Revista: Eur J Pharm Sci Asunto de la revista: FARMACIA / FARMACOLOGIA / QUIMICA Año: 2015 Tipo del documento: Article Pais de publicación: Países Bajos

Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Asunto principal: Beta-Ciclodextrinas / Excipientes Idioma: En Revista: Eur J Pharm Sci Asunto de la revista: FARMACIA / FARMACOLOGIA / QUIMICA Año: 2015 Tipo del documento: Article Pais de publicación: Países Bajos