Copper(I)-catalyzed heteroannulation of [60]fullerene with ketoxime acetates: preparation of novel 1-fulleropyrrolines.

Jiang, Sheng-Peng; Su, Yi-Tan; Liu, Kai-Qing; Wu, Qing-Hua; Wang, Guan-Wu

Jiang, Sheng-Peng; Su, Yi-Tan; Liu, Kai-Qing; Wu, Qing-Hua; Wang, Guan-Wu.

Afiliación

Jiang SP; CAS Key Laboratory of Soft Matter Chemistry, Collaborative Innovation Center of Chemistry for Energy Materials, Hefei National Laboratory for Physical Sciences at Microscale and Department of Chemistry, University of Science and Technology of China, Hefei, Anhui 230026, P. R. China. gwang@ustc.edu.cn.

Chem Commun (Camb) ; 51(30): 6548-51, 2015 Apr 18.

Article en En | MEDLINE | ID: mdl-25766768

RESUMEN

A cuprous bromide-catalyzed heteroannulation reaction of [60]fullerene with ketoxime acetates has been exploited to prepare novel 1-fulleropyrrolines through the cleavage of N-O and C-H bonds and formation of C-C and C-N bonds under thermal conditions. A plausible mechanism for the formation of 1-fulleropyrrolines is proposed on the basis of the experimental results. The electrochemistry of the obtained products has also been investigated.

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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Chem Commun (Camb) Asunto de la revista: QUIMICA Año: 2015 Tipo del documento: Article Pais de publicación: Reino Unido

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