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H2O2 release from the very long chain acyl-CoA dehydrogenase.
Kakimoto, Pâmela A H B; Tamaki, Fábio K; Cardoso, Ariel R; Marana, Sandro R; Kowaltowski, Alicia J.
Afiliación
  • Kakimoto PA; Departamento de Bioquímica, Instituto de Química, Universidade de São Paulo, Av. Prof. Lineu Prestes, 748, Cidade Universitária, 05508-000 São Paulo, SP, Brazil.
  • Tamaki FK; Departamento de Bioquímica, Instituto de Química, Universidade de São Paulo, Av. Prof. Lineu Prestes, 748, Cidade Universitária, 05508-000 São Paulo, SP, Brazil.
  • Cardoso AR; Departamento de Bioquímica, Instituto de Química, Universidade de São Paulo, Av. Prof. Lineu Prestes, 748, Cidade Universitária, 05508-000 São Paulo, SP, Brazil.
  • Marana SR; Departamento de Bioquímica, Instituto de Química, Universidade de São Paulo, Av. Prof. Lineu Prestes, 748, Cidade Universitária, 05508-000 São Paulo, SP, Brazil.
  • Kowaltowski AJ; Departamento de Bioquímica, Instituto de Química, Universidade de São Paulo, Av. Prof. Lineu Prestes, 748, Cidade Universitária, 05508-000 São Paulo, SP, Brazil. Electronic address: alicia@iq.usp.br.
Redox Biol ; 4: 375-80, 2015.
Article en En | MEDLINE | ID: mdl-25728796
Enhanced mitochondrial generation of oxidants, including hydrogen peroxide (H2O2), is related to a large number of pathological conditions, including diet-induced obesity and steatohepatosis. Indeed, we have previously shown that high fat diets increase the generation of H2O2 in liver mitochondria energized by activated fatty acids. Here, we further study fatty-acid induced H2O2 release in liver mitochondria, and determine the characteristics that regulate it. We find that this production of H2O2 is independent of mitochondrial inner membrane integrity and insensitive to purine nucleotides. On the other hand, palmitate-induced H2O2 production is strongly enhanced by high fat diets and is pH-sensitive, with a peak at a matrix pH of ~8.5. Using recombinantly expressed human very long chain acyl-CoA dehydrogenase, we are able to demonstrate that palmitate-induced H2O2 release may be ascribed to the activity of this enzyme alone, acting as an oxidase. Our results add to a number of findings indicating that sources outside of the electron transport chain can generate significant, physiopathologically relevant, amounts of oxidants in mitochondria.
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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Asunto principal: Mitocondrias Hepáticas / Acil-CoA Deshidrogenasa de Cadena Larga / Dieta Alta en Grasa / Peróxido de Hidrógeno Límite: Animals Idioma: En Revista: Redox Biol Año: 2015 Tipo del documento: Article País de afiliación: Brasil Pais de publicación: Países Bajos

Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Asunto principal: Mitocondrias Hepáticas / Acil-CoA Deshidrogenasa de Cadena Larga / Dieta Alta en Grasa / Peróxido de Hidrógeno Límite: Animals Idioma: En Revista: Redox Biol Año: 2015 Tipo del documento: Article País de afiliación: Brasil Pais de publicación: Países Bajos