Direct enantiospecific substitution of primary &#945;-aminoalkylferrocenes via Lewis acid-catalyzed C-N bond cleavage.

Zhou, Meng-Guang; Zhang, Wen-Zhao; Tian, Shi-Kai

Direct enantiospecific substitution of primary α-aminoalkylferrocenes via Lewis acid-catalyzed C-N bond cleavage.

Zhou, Meng-Guang; Zhang, Wen-Zhao; Tian, Shi-Kai.

Afiliación

Zhou MG; Department of Chemistry, University of Science and Technology of China, Hefei, Anhui 230026, China. tiansk@ustc.edu.cn.

Chem Commun (Camb) ; 50(93): 14531-4, 2014 Dec 04.

Article en En | MEDLINE | ID: mdl-25307165

RESUMEN

Highly enantioenriched primary α-aminoalkylferrocenes were found to undergo zinc chloride-catalyzed substitution with various carbon, nitrogen, and sulfur nucleophiles in an enantiospecific fashion through C-N bond cleavage. The reaction tolerates air and moisture and exhibits high atom-economy by releasing ammonia as the sole byproduct.

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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Chem Commun (Camb) Asunto de la revista: QUIMICA Año: 2014 Tipo del documento: Article País de afiliación: China Pais de publicación: Reino Unido

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