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Design, synthesis and pharmacological evaluation of chalcone derivatives as acetylcholinesterase inhibitors.
Liu, Hao-ran; Liu, Xian-jun; Fan, Hao-qun; Tang, Jing-jing; Gao, Xiao-hui; Liu, Wu-Kun.
Afiliación
  • Liu HR; College of Chemistry and Chemical Engineering, Hu'nan University, Changsha 410082, China. Electronic address: pharmaliu@126.com.
  • Liu XJ; College of Chemistry and Chemical Engineering, Hu'nan University, Changsha 410082, China.
  • Fan HQ; College of Chemistry and Chemical Engineering, Hu'nan University, Changsha 410082, China.
  • Tang JJ; College of Chemistry and Chemical Engineering, Hu'nan University, Changsha 410082, China.
  • Gao XH; College of Pharmacy, Hu'nan University of Traditional Chinese Medicine (TCM), Changsha 410208, China.
  • Liu WK; College of Chemistry and Chemical Engineering, Hu'nan University, Changsha 410082, China.
Bioorg Med Chem ; 22(21): 6124-33, 2014 Nov 01.
Article en En | MEDLINE | ID: mdl-25260958
A novel series of chalcone derivatives (4a-8d) were designed, synthesized, and evaluated for the inhibition activity against acetylcholinesterase (AChE) and butyrylcholinesterase (BuChE). The logP values of the compounds were shown to range from 1.49 to 2.19, which suggested that they were possible to pass blood brain barriers in vivo. The most promising compound 4a (IC50: 4.68 µmol/L) was 2-fold more potent than Rivastigmine against AChE (IC50: 10.54 µmol/L) and showed a high selectivity for AChE over BuChE (ratio: 4.35). Enzyme kinetic study suggested that the inhibition mechanism of compound 4a was a mixed-type inhibition. Meanwhile, the result of molecular docking showed its potent inhibition of AChE and high selectivity for AChE over BuChE.
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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Asunto principal: Acetilcolinesterasa / Chalcona / Inhibidores de la Colinesterasa Límite: Animals / Humans Idioma: En Revista: Bioorg Med Chem Asunto de la revista: BIOQUIMICA / QUIMICA Año: 2014 Tipo del documento: Article Pais de publicación: Reino Unido

Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Asunto principal: Acetilcolinesterasa / Chalcona / Inhibidores de la Colinesterasa Límite: Animals / Humans Idioma: En Revista: Bioorg Med Chem Asunto de la revista: BIOQUIMICA / QUIMICA Año: 2014 Tipo del documento: Article Pais de publicación: Reino Unido