Ru-catalyzed rearrangement of N-methyl isoxazolidines to N-H 1,3-oxazinanes: a strategy of self-hydride transferring cleavage of N-O bonds.

Yao, Chuan-Zhi; Xiao, Zu-Feng; Liu, Jie; Ning, Xiao-Shan; Kang, Yan-Biao

Yao, Chuan-Zhi; Xiao, Zu-Feng; Liu, Jie; Ning, Xiao-Shan; Kang, Yan-Biao.

Afiliación

Yao CZ; Department of Chemistry, University of Science and Technology of China , 96 Jinzhai Road, Hefei, Anhui 230026, China.

Org Lett ; 16(9): 2498-501, 2014 May 02.

Article en En | MEDLINE | ID: mdl-24735063

RESUMEN

A strategy of ruthenium-catalyzed self-hydride transferring cleavage of N-O bonds was designed and utilized in a cascade 1,3-dipolar cyclization of alkenes and N-methyl nitrones followed by an N-demethylative rearrangement, furnishing synthetically useful N-H 1,3-oxazinanes.

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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Org Lett Asunto de la revista: BIOQUIMICA Año: 2014 Tipo del documento: Article País de afiliación: China Pais de publicación: Estados Unidos

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