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Highly enantioselective kinetic resolution of axially chiral BINAM derivatives catalyzed by a Brønsted acid.
Cheng, Dao-Juan; Yan, Liang; Tian, Shi-Kai; Wu, Ming-Yue; Wang, Lu-Xin; Fan, Zi-Li; Zheng, Sheng-Cai; Liu, Xin-Yuan; Tan, Bin.
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  • Cheng DJ; Department of Chemistry, South University of Science and Technology of China, Shenzhen, 518055 (China).
Angew Chem Int Ed Engl ; 53(14): 3684-7, 2014 Apr 01.
Article en En | MEDLINE | ID: mdl-24591330
A highly efficient strategy for the kinetic resolution of axially chiral BINAM derivatives involving a chiral Brønsted acid-catalyzed imine formation and transfer hydrogenation cascade process was developed. The kinetic resolution provides a convenient route to chiral BINAM derivatives in high yields with excellent enantioselectivities.
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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Angew Chem Int Ed Engl Año: 2014 Tipo del documento: Article Pais de publicación: Alemania
Texto completo
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Imprimir
XML
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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Angew Chem Int Ed Engl Año: 2014 Tipo del documento: Article Pais de publicación: Alemania