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Towards waste free organic synthesis using nanostructured hybrid silicas.
Ciriminna, Rosaria; Ilharco, Laura M; Pandarus, Valerica; Fidalgo, Alexandra; Béland, François; Pagliaro, Mario.
Afiliación
  • Ciriminna R; Istituto per lo Studio dei Materiali Nanostrutturati, CNR, via U. La Malfa 153, 90146 Palermo, Italy. mario.pagliaro@cnr.it.
Nanoscale ; 6(12): 6293-300, 2014 Jun 21.
Article en En | MEDLINE | ID: mdl-24584712
As catalysis and organic synthesis come together again, the need for stable, selective and truly heterogeneous solid catalysts for clean and efficient synthetic organic chemistry has increased. Hybrid silica glasses obtained by the sol-gel nanochemistry approach can be successfully used for the waste-free synthesis of valued chemicals in various applications. This success derives from the deliberate chemical design of hybrid nanostructures capable of immobilizing and stabilizing organocatalytic species and unstable metal nanoparticles. The highly selective activity along with a broad scope and ease of application of these mesoporous materials to high-throughput reactions opens the route to faster, cleaner and more convenient processes for both small and large scale manufacturing of useful molecules.

Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Nanoscale Año: 2014 Tipo del documento: Article País de afiliación: Italia Pais de publicación: Reino Unido

Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Nanoscale Año: 2014 Tipo del documento: Article País de afiliación: Italia Pais de publicación: Reino Unido