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S-Nitrosation of monocarboxylate transporter 1: inhibition of pyruvate-fueled respiration and proliferation of breast cancer cells.
Diers, Anne R; Broniowska, Katarzyna A; Chang, Ching-Fang; Hill, R Blake; Hogg, Neil.
Afiliación
  • Diers AR; Department of Biophysics, Medical College of Wisconsin, Milwaukee, WI 53226, USA; Redox Biology Program, Medical College of Wisconsin, Milwaukee, WI 53226, USA. Electronic address: annerdiers@gmail.com.
  • Broniowska KA; Department of Biophysics, Medical College of Wisconsin, Milwaukee, WI 53226, USA; Redox Biology Program, Medical College of Wisconsin, Milwaukee, WI 53226, USA.
  • Chang CF; Department of Biophysics, Medical College of Wisconsin, Milwaukee, WI 53226, USA; Redox Biology Program, Medical College of Wisconsin, Milwaukee, WI 53226, USA.
  • Hill RB; Department of Biochemistry, Medical College of Wisconsin, Milwaukee, WI 53226, USA.
  • Hogg N; Department of Biophysics, Medical College of Wisconsin, Milwaukee, WI 53226, USA; Redox Biology Program, Medical College of Wisconsin, Milwaukee, WI 53226, USA.
Free Radic Biol Med ; 69: 229-38, 2014 Apr.
Article en En | MEDLINE | ID: mdl-24486553
Energy substrates metabolized through mitochondria (e.g., pyruvate, glutamine) are required for biosynthesis of macromolecules in proliferating cells. Because several mitochondrial proteins are known to be targets of S-nitrosation, we determined whether bioenergetics are modulated by S-nitrosation and defined the subsequent effects on proliferation. The nitrosating agent S-nitroso-L-cysteine (L-CysNO) was used to initiate intracellular S-nitrosation, and treatment decreased mitochondrial function and inhibited proliferation of MCF7 mammary adenocarcinoma cells. Surprisingly, the d-isomer of CysNO (D-CysNO), which is not transported into cells, also caused mitochondrial dysfunction and limited proliferation. Both L- and D-CysNO also inhibited cellular pyruvate uptake and caused S-nitrosation of thiol groups on monocarboxylate transporter 1, a proton-linked pyruvate transporter. These data demonstrate the importance of mitochondrial metabolism in proliferative responses in breast cancer and highlight a novel role for inhibition of metabolic substrate uptake through S-nitrosation of exofacial protein thiols in cellular responses to nitrosative stress.
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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Asunto principal: Nitrosación / Ácido Pirúvico / Transportadores de Ácidos Monocarboxílicos / Simportadores / Mitocondrias Límite: Humans Idioma: En Revista: Free Radic Biol Med Asunto de la revista: BIOQUIMICA / MEDICINA Año: 2014 Tipo del documento: Article Pais de publicación: Estados Unidos

Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Asunto principal: Nitrosación / Ácido Pirúvico / Transportadores de Ácidos Monocarboxílicos / Simportadores / Mitocondrias Límite: Humans Idioma: En Revista: Free Radic Biol Med Asunto de la revista: BIOQUIMICA / MEDICINA Año: 2014 Tipo del documento: Article Pais de publicación: Estados Unidos