Your browser doesn't support javascript.
loading
A tetravalent cerium complex containing a Ce=O bond.
So, Yat-Ming; Wang, Guo-Cang; Li, Yang; Sung, Herman H-Y; Williams, Ian D; Lin, Zhenyang; Leung, Wa-Hung.
Afiliación
  • So YM; Department of Chemistry, The Hong Kong University of Science and Technology, Clear Water Bay, Kowloon, Hong Kong (China).
Angew Chem Int Ed Engl ; 53(6): 1626-9, 2014 Feb 03.
Article en En | MEDLINE | ID: mdl-24403106
Whereas terminal oxo complexes of transition and actinide elements are well documented, analogous lanthanide complexes have not been reported to date. Herein, we report the synthesis and structure of a cerium(IV) oxo complex, [CeO(LOEt )2 (H2 O)]⋅MeC(O)NH2 (1; LOEt (-) =[Co(η(5) -C5 H5 ){P(O)(OEt)2 }3 ](-) ), featuring a short CeO bond (1.857(3) Å). DFT calculations indicate that the hydrogen bond to cocrystallized acetamide plays a key role in stabilizing the CeO moiety of 1 in the solid state. Complex 1 exhibits oxidizing and nucleophilic reactivity.
Asunto(s)
Palabras clave
Texto completo
Añadir a Mi BVS
Imprimir
XML
PubMed Links
Buscar en Google

Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Asunto principal: Cerio / Complejos de Coordinación Idioma: En Revista: Angew Chem Int Ed Engl Año: 2014 Tipo del documento: Article Pais de publicación: Alemania
Texto completo
Añadir a Mi BVS
Imprimir
XML
PubMed Links
Buscar en Google

Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Asunto principal: Cerio / Complejos de Coordinación Idioma: En Revista: Angew Chem Int Ed Engl Año: 2014 Tipo del documento: Article Pais de publicación: Alemania