New cobalt, iron and chromium catalysts based on easy-to-handle N4-chelating ligands for the coupling reaction of epoxides with CO2.

Adolph, M; Zevaco, T A; Altesleben, C; Walter, O; Dinjus, E

Adolph, M; Zevaco, T A; Altesleben, C; Walter, O; Dinjus, E.

Afiliación

Adolph M; Institut für Katalyseforschung und -Technologie (IKFT), Karlsruher Institut für Technologie (KIT), Hermann-von-Helmholtz-Platz 1, 76344 Eggenstein-Leopoldshafen, Germany. thomas.zevaco@kit.edu eckhard.dinjus@kit.edu.

Dalton Trans ; 43(8): 3285-96, 2014 Feb 28.

Article en En | MEDLINE | ID: mdl-24362452

RESUMEN

In this contribution, we report the successful utilization of several transition metal complexes based on substituted N4-N,N-bis(2-pyridinecarboxamide)-1,2-benzene chelating ligands as catalysts in the coupling of epoxides with carbon dioxide. The complexes were tested towards cyclohexene oxide and propylene oxide. Additionally the recyclability of the catalytic system was evaluated and a broader catalytic screening involving several commercially available epoxides was carried out with selected catalysts.

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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Dalton Trans Asunto de la revista: QUIMICA Año: 2014 Tipo del documento: Article Pais de publicación: Reino Unido

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