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Molecular modeling and analysis of hepatitis E virus (HEV) papain-like cysteine protease.
Parvez, Mohammad Khalid; Khan, Azmat Ali.
Afiliación
  • Parvez MK; Department of Pharmacognosy, King Saud University College of Pharmacy, Riyadh 11451, Saudi Arabia. Electronic address: Khalid_parve@yahoo.com.
  • Khan AA; Department of Pharmaceutical Chemistry, King Saud University College of Pharmacy, Riyadh 11451, Saudi Arabia.
Virus Res ; 179: 220-4, 2014 Jan 22.
Article en En | MEDLINE | ID: mdl-24321124
The biochemical or biophysical characterization of a papain-like cysteine protease in HEV ORF1-encoded polyprotein still remains elusive. Very recently, we have demonstrated the indispensability of ORF1 protease-domain cysteines and histidines in HEV replication, ex vivo (Parvez, 2013). In this report, the polyprotein partial sequences of HEV strains and genetically-related RNA viruses were analyzed, in silico. Employing the consensus-prediction results of RUBV-p(150) protease as structural-template, a 3D model of HEV-protease was deduced. Similar to RUBV-p(150), a 'papain-like ß-barrel fold' structurally confirmed the classification of HEV-protease. Further, we recognized a catalytic 'Cys434-His443' dyad homologue of RUBV-p(150) (Cys1152-His1273) and FMDV-L(pro) (Cys51-His148) in line with our previous mutational analysis that showed essentiality of 'His443' but not 'His590' in HEV viability. Moreover, a RUBV 'Zn(2+) binding motif' (Cys1167-Cys1175-Cys1178-Cys1225-Cys1227) equivalent of HEV was identified as 'Cys457-His458-Cys459 and Cys481-Cys483' residues within the 'ß-barrel fold'. Notably, unlike RUBV, 'His458' also clustered therein, that was in conformity with the consensus cysteine protease 'Zn(2+)-binding motif'. By homology, we also proposed an overlapping 'Ca(2+)-binding site' 'D-X-[DNS]-[ILVFYW]-[DEN]-G-[GP]-XX-DE' signature, and a 'proline-rich motif' interacting 'tryptophan (W437-W472)' module in the modeled structure. Our analysis of the predicted model therefore, warrants critical roles of the 'catalytic dyad' and 'divalent metal-binding motifs' in HEV protease structural-integrity, ORF1 self-processing, and RNA replication. This however, needs further experimental validations.
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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Asunto principal: Proteínas Virales / Virus de la Hepatitis E / Proteasas de Cisteína Tipo de estudio: Prognostic_studies Idioma: En Revista: Virus Res Asunto de la revista: VIROLOGIA Año: 2014 Tipo del documento: Article Pais de publicación: Países Bajos

Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Asunto principal: Proteínas Virales / Virus de la Hepatitis E / Proteasas de Cisteína Tipo de estudio: Prognostic_studies Idioma: En Revista: Virus Res Asunto de la revista: VIROLOGIA Año: 2014 Tipo del documento: Article Pais de publicación: Países Bajos