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Optimization of potency and pharmacokinetics of tricyclic indole derived inhibitors of HCV NS5B polymerase. Identification of ester prodrugs with improved oral pharmacokinetics.
Venkatraman, Srikanth; Velazquez, Francisco; Gavalas, Stephen; Wu, Wanli; Chen, Kevin X; Nair, Anilkumar G; Bennett, Frank; Huang, Yuhua; Pinto, Patrick; Jiang, Yueheng; Selyutin, Oleg; Vibulbhan, Bancha; Zeng, Qingbei; Lesburg, Charles; Duca, Jose; Heimark, Larry; Huang, Hsueh-Cheng; Agrawal, Sony; Jiang, Chuan-kui; Ferrari, Eric; Li, Cheng; Kozlowski, Joseph; Rosenblum, Stuart; Shih, Neng-Yang; Njoroge, F George.
Afiliación
  • Venkatraman S; Merck Research Laboratories, K15, 2015 Galloping Hill Road, Kenilworth, NJ 07033, United States. Electronic address: Srikanth.Venkatraman@merck.com.
  • Velazquez F; Merck Research Laboratories, K15, 2015 Galloping Hill Road, Kenilworth, NJ 07033, United States.
  • Gavalas S; Merck Research Laboratories, K15, 2015 Galloping Hill Road, Kenilworth, NJ 07033, United States.
  • Wu W; Merck Research Laboratories, K15, 2015 Galloping Hill Road, Kenilworth, NJ 07033, United States.
  • Chen KX; Merck Research Laboratories, K15, 2015 Galloping Hill Road, Kenilworth, NJ 07033, United States.
  • Nair AG; Merck Research Laboratories, K15, 2015 Galloping Hill Road, Kenilworth, NJ 07033, United States.
  • Bennett F; Merck Research Laboratories, K15, 2015 Galloping Hill Road, Kenilworth, NJ 07033, United States.
  • Huang Y; Merck Research Laboratories, K15, 2015 Galloping Hill Road, Kenilworth, NJ 07033, United States.
  • Pinto P; Merck Research Laboratories, K15, 2015 Galloping Hill Road, Kenilworth, NJ 07033, United States.
  • Jiang Y; Merck Research Laboratories, K15, 2015 Galloping Hill Road, Kenilworth, NJ 07033, United States.
  • Selyutin O; Merck Research Laboratories, K15, 2015 Galloping Hill Road, Kenilworth, NJ 07033, United States.
  • Vibulbhan B; Merck Research Laboratories, K15, 2015 Galloping Hill Road, Kenilworth, NJ 07033, United States.
  • Zeng Q; Merck Research Laboratories, K15, 2015 Galloping Hill Road, Kenilworth, NJ 07033, United States.
  • Lesburg C; Merck Research Laboratories, K15, 2015 Galloping Hill Road, Kenilworth, NJ 07033, United States.
  • Duca J; Merck Research Laboratories, K15, 2015 Galloping Hill Road, Kenilworth, NJ 07033, United States.
  • Heimark L; Merck Research Laboratories, K15, 2015 Galloping Hill Road, Kenilworth, NJ 07033, United States.
  • Huang HC; Merck Research Laboratories, K15, 2015 Galloping Hill Road, Kenilworth, NJ 07033, United States.
  • Agrawal S; Merck Research Laboratories, K15, 2015 Galloping Hill Road, Kenilworth, NJ 07033, United States.
  • Jiang CK; Merck Research Laboratories, K15, 2015 Galloping Hill Road, Kenilworth, NJ 07033, United States.
  • Ferrari E; Merck Research Laboratories, K15, 2015 Galloping Hill Road, Kenilworth, NJ 07033, United States.
  • Li C; Merck Research Laboratories, K15, 2015 Galloping Hill Road, Kenilworth, NJ 07033, United States.
  • Kozlowski J; Merck Research Laboratories, K15, 2015 Galloping Hill Road, Kenilworth, NJ 07033, United States.
  • Rosenblum S; Merck Research Laboratories, K15, 2015 Galloping Hill Road, Kenilworth, NJ 07033, United States.
  • Shih NY; Merck Research Laboratories, K15, 2015 Galloping Hill Road, Kenilworth, NJ 07033, United States.
  • Njoroge FG; Merck Research Laboratories, K15, 2015 Galloping Hill Road, Kenilworth, NJ 07033, United States.
Bioorg Med Chem ; 22(1): 447-58, 2014 Jan 01.
Article en En | MEDLINE | ID: mdl-24275348
HCV infections are the leading causes for hepatocellular carcinoma and liver transplantation in the United States. Recent advances in drug discovery have identified direct acting antivirals which have significantly improved cure rates in patients. Current efforts are directed towards identification of novel direct acting antiviral targeting different mechanism of actions which could become part of all oral therapies. We recently disclosed the identification of a novel tricyclic indole derived inhibitors of HCV NS5B polymerase that bound to the enzyme close to the active site. In this manuscript we describe further optimization of potency and pharmacokinetics (PK) of these inhibitors to identify compounds in low nM potency against gt-1b. These analogs also demonstrate excellent PK in rats and monkeys when administered as a dimethyl ethyl amino ester prodrug.
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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Asunto principal: Proteínas no Estructurales Virales / Hepacivirus / Ésteres / Indoles Tipo de estudio: Diagnostic_studies Límite: Animals / Humans Idioma: En Revista: Bioorg Med Chem Asunto de la revista: BIOQUIMICA / QUIMICA Año: 2014 Tipo del documento: Article Pais de publicación: Reino Unido

Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Asunto principal: Proteínas no Estructurales Virales / Hepacivirus / Ésteres / Indoles Tipo de estudio: Diagnostic_studies Límite: Animals / Humans Idioma: En Revista: Bioorg Med Chem Asunto de la revista: BIOQUIMICA / QUIMICA Año: 2014 Tipo del documento: Article Pais de publicación: Reino Unido