Enhancing optical absorption of metal-organic frameworks for improved visible light photocatalysis.

Nasalevich, Maxim A; Goesten, Maarten G; Savenije, Tom J; Kapteijn, Freek; Gascon, Jorge

Nasalevich, Maxim A; Goesten, Maarten G; Savenije, Tom J; Kapteijn, Freek; Gascon, Jorge.

Afiliación

Nasalevich MA; Catalysis Engineering, Department of Chemical Engineering, Delft University of Technology, Julianalaan 136, Delft, 2628 BL, The Netherlands. M.Nasalevich@tudelft.nl J.Gascon@tudelft.nl.

Chem Commun (Camb) ; 49(90): 10575-7, 2013 Nov 21.

Article en En | MEDLINE | ID: mdl-24091538

RESUMEN

NH2-MIL-125(Ti) has been post-synthetically functionalized with dye-like molecular fragments. The new material (methyl red-MIL-125(Ti)) exhibits improved light absorption over a wide range of the visible spectrum, and shows enhanced photocatalytic oxidation activity under visible light illumination. The consequences of functionalization and the bottlenecks in MOF photochemistry are studied in detail.

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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Chem Commun (Camb) Asunto de la revista: QUIMICA Año: 2013 Tipo del documento: Article Pais de publicación: Reino Unido

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