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Synthesis of new pyrimidine-fused derivatives as potent and selective antidiabetic α-glucosidase inhibitors.
Panahi, Farhad; Yousefi, Reza; Mehraban, Mohammad Hossein; Khalafi-Nezhad, Ali.
Afiliación
  • Panahi F; Protein Chemistry Laboratory (PCL), Department of Biology, College of Sciences, Shiraz University, Shiraz, Iran; Department of Chemistry, College of Sciences, Shiraz University, Shiraz 71454, Iran.
Carbohydr Res ; 380: 81-91, 2013 Oct 18.
Article en En | MEDLINE | ID: mdl-23978663
The synthesis of a set of pyrimidine-fused derivatives (L1-L8), resulting from the incorporation of different fragments on the pyrimidine-fused heterocycle (PFH) of the earlier reported α-glucosidase (α-Gls) inhibitor (C1-C5), allowed the discovery of new ligands with modest and selective inhibitory activity. The PFH core (substructure 2) was proved to play a significant role in their inhibitory properties. Additionally, the substituent on substructures 1 and 3 of the heterocyclic ring was demonstrated to be important in the enzyme inhibitory action of the pyrimidine-fused derivatives. Moreover, these ligands show selective inhibitory properties for α-Gls over porcine pancreatic α-amylase (α-Amy) which is important in terms of their reduced susceptibility for the possible development of intestinal disturbance side effects. Therefore, low to moderate α-Amy inhibition with effective α-Gls inhibitory action may offer a better therapeutic strategy. Overall, these compounds can potentially offer a new opportunity to develop novel antidiabetic drugs with selective inhibitory action against α-Gls.
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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Asunto principal: Pirimidinas / Inhibidores de Glicósido Hidrolasas / Hipoglucemiantes Límite: Animals Idioma: En Revista: Carbohydr Res Año: 2013 Tipo del documento: Article País de afiliación: Irán Pais de publicación: Países Bajos

Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Asunto principal: Pirimidinas / Inhibidores de Glicósido Hidrolasas / Hipoglucemiantes Límite: Animals Idioma: En Revista: Carbohydr Res Año: 2013 Tipo del documento: Article País de afiliación: Irán Pais de publicación: Países Bajos