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Bias of apparent tracer ages in heterogeneous environments.
McCallum, James L; Cook, Peter G; Simmons, Craig T; Werner, Adrian D.
Afiliación
  • McCallum JL; School of the Environment, Flinders University, Adelaide, South Australia, Australia.
Ground Water ; 52(2): 239-50, 2014.
Article en En | MEDLINE | ID: mdl-23550995
The interpretation of apparent ages often assumes that a water sample is composed of a single age. In heterogeneous aquifers, apparent ages estimated with environmental tracer methods do not reflect mean water ages because of the mixing of waters from many flow paths with different ages. This is due to nonlinear variations in atmospheric concentrations of the tracer with time resulting in biases of mixed concentrations used to determine apparent ages. The bias of these methods is rarely reported and has not been systematically evaluated in heterogeneous settings. We simulate residence time distributions (RTDs) and environmental tracers CFCs, SF6 , (85) Kr, and (39) Ar in synthetic heterogeneous confined aquifers and compare apparent ages to mean ages. Heterogeneity was simulated as both K-field variance (σ(2) ) and structure. We demonstrate that an increase in heterogeneity (increase in σ(2) or structure) results in an increase in the width of the RTD. In low heterogeneity cases, widths were generally on the order of 10 years and biases generally less than 10%. In high heterogeneity cases, widths can reach 100 s of years and biases can reach up to 100%. In cases where the temporal variations of atmospheric concentration of individual tracers vary, different patterns of bias are observed for the same mean age. We show that CFC-12 and CFC-113 ages may be used to correct for the mean age if analytical errors are small.
Asunto(s)

Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Asunto principal: Movimientos del Agua / Agua Subterránea / Monitoreo del Ambiente Idioma: En Revista: Ground Water Asunto de la revista: SAUDE AMBIENTAL / TOXICOLOGIA Año: 2014 Tipo del documento: Article País de afiliación: Australia Pais de publicación: Estados Unidos

Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Asunto principal: Movimientos del Agua / Agua Subterránea / Monitoreo del Ambiente Idioma: En Revista: Ground Water Asunto de la revista: SAUDE AMBIENTAL / TOXICOLOGIA Año: 2014 Tipo del documento: Article País de afiliación: Australia Pais de publicación: Estados Unidos