catena-Poly[sodium-µ2-(N,N,N',N'-tetra-methyl-ethane-1,2-diamine)-&#954;(2) N:N'-sodium-bis-[µ2-bis-(trimethyl-sil-yl)aza-nido-&#954;(2) N:N]].

Kennedy, Alan R; Mulvey, Robert E; O'Hara, Charles T; Robertson, Stuart D; Robertson, Gemma M

catena-Poly[sodium-µ2-(N,N,N',N'-tetra-methyl-ethane-1,2-diamine)-κ(2) N:N'-sodium-bis-[µ2-bis-(trimethyl-sil-yl)aza-nido-κ(2) N:N]].

Kennedy, Alan R; Mulvey, Robert E; O'Hara, Charles T; Robertson, Stuart D; Robertson, Gemma M.

Afiliación

Kennedy AR; WestCHEM, Department of Pure and Applied Chemistry, University of Strathclyde, 295 Cathedral Street, Glasgow G1 1XL, Scotland.

Acta Crystallogr Sect E Struct Rep Online ; 68(Pt 12): m1468, 2012 Dec 01.

Article en En | MEDLINE | ID: mdl-23468695

RESUMEN

The title compound, [Na2(C6H18NSi2)2(C6H16N2)] n , was found to consist of dimeric [Na(NSiMe3)2] units with crystallographically imposed centrosymmetry based upon four-membered NaNNaN rings. The dimers are bridged by N,N,N',N'-tetra-methyl-ethylenediamine ligands, which act in an unusual extended non-chelating coordination mode. This gives a one-dimensional coordination polymer that extends parallel to the a-axis direction.

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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Acta Crystallogr Sect E Struct Rep Online Año: 2012 Tipo del documento: Article País de afiliación: Reino Unido Pais de publicación: Estados Unidos

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