The oxidative mechanism in electrophilic C-H activation: the case of CH2F2 and CH2Cl2.
Chem Asian J
; 8(3): 588-95, 2013 Mar.
Article
en En
| MEDLINE
| ID: mdl-23297066
The H(.)-atom transfer (HAT) reaction is investigated in the gas phase, starting from two different entrance channels, O(2)(.+)/CH(2)X(2) and CH(2)X(2)(.+)/O(2) (X=F, Cl), that correspond to a step of hydride transfer and to HAT, respectively. Analysis of the spin and charge along the reaction pathway shows that HAT occurs through the same reacting configuration, irrespective of whether the reactants are formed within the complex or are free isolated species.
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1
Colección:
01-internacional
Base de datos:
MEDLINE
Idioma:
En
Revista:
Chem Asian J
Año:
2013
Tipo del documento:
Article
País de afiliación:
Italia
Pais de publicación:
Alemania