A new dabco-templated metal sulfate: 1,4-diazo-niabicyclo-[2.2.2]octane hexa-aqua-cadmium bis-(sulfate).
Acta Crystallogr Sect E Struct Rep Online
; 68(Pt 6): m759-60, 2012 Jun 01.
Article
en En
| MEDLINE
| ID: mdl-22719318
The title double mol-ecular salt, (C(6)H(14)N(2))[Cd(H(2)O)(6)](SO(4))(2), is an isostructure of its Mn and Co analogues. The Cd(II) atom adopts a near-regular CdO(6) octa-hedral coordination geometry. The crystal structure can be described as an alternation of cationic and anionic layers along [010], and numerous O-Hâ¯O and N-Hâ¯O hydrogen bonds are observed. No thermal anomalies corresponding to possible phase transitions were observed in DSC (differential scanning calorimetry) measurements and the 93â
K structure is almost the same as the room-temperature structure.
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01-internacional
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En
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Acta Crystallogr Sect E Struct Rep Online
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2012
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Article
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Estados Unidos