Bis(azido-κN)bis-[6-(pyridin-2-yl)-1,3,5-triazine-2,4-diamine-κ(2)N(1),N(6)]manganese(II).
Acta Crystallogr Sect E Struct Rep Online
; 68(Pt 4): m427, 2012 Apr 01.
Article
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| MEDLINE
| ID: mdl-22589803
In the title complex, [Mn(N(3))(2)(C(8)H(8)N(6))(2)], the complete molecule is generated by the application of twofold symmetry, and is in a distorted octa-hedral environment, coordinated by four N atoms of two bidentate 6-(pyridin-2-yl)-1,3,5-triazine-2,4-diamine ligands and two N atoms from two azide anions. The two chelated 6-(pyridin-2-yl)-1,3,5-triazine-2,4-diamine ligands form a dihedral angle 74.75â
(5)°. The mononuclear mol-ecules are alternatively linked into layers parallel to the ac plane via N-Hâ¯N hydrogen bonds. Adjacent layers are connected into a three-dimensional supra-molecular framework by futher N-Hâ¯N hydrogen-bonding inter-actions.
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01-internacional
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MEDLINE
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En
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Acta Crystallogr Sect E Struct Rep Online
Año:
2012
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Article
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Estados Unidos