NH2-MIL-53(Al): a high-contrast reversible solid-state nonlinear optical switch.

Serra-Crespo, Pablo; van der Veen, Monique A; Gobechiya, Elena; Houthoofd, Kristof; Filinchuk, Yaroslav; Kirschhock, Christine E A; Martens, Johan A; Sels, Bert F; De Vos, Dirk E; Kapteijn, Freek; Gascon, Jorge

Serra-Crespo, Pablo; van der Veen, Monique A; Gobechiya, Elena; Houthoofd, Kristof; Filinchuk, Yaroslav; Kirschhock, Christine E A; Martens, Johan A; Sels, Bert F; De Vos, Dirk E; Kapteijn, Freek; Gascon, Jorge.

Afiliación

Serra-Crespo P; Catalysis Engineering, Chemical Engineering Department, Delft University of Technology, The Netherlands.

J Am Chem Soc ; 134(20): 8314-7, 2012 May 23.

Article en En | MEDLINE | ID: mdl-22578194

RESUMEN

The metal-organic framework NH(2)-MIL-53(Al) is the first solid-state material displaying nonlinear optical switching due to a conformational change upon breathing. A switching contrast of at least 38 was observed. This transition originates in the restrained linker mobility in the very narrow pore configuration.

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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: J Am Chem Soc Año: 2012 Tipo del documento: Article País de afiliación: Países Bajos Pais de publicación: Estados Unidos

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