Shifting from Ziegler-Natta to Philips-type catalyst? A simple and safe access to reduced titanium systems for ethylene polymerization.
Macromol Rapid Commun
; 32(23): 1921-4, 2011 Dec 01.
Article
en En
| MEDLINE
| ID: mdl-21948353
Silica-supported titanium(IV) chloride is readily reduced by Mashima and co-workers' reagent (1-methyl-3,6-bis(trimethylsilyl)-1,4-cyclohexadiene) to afford materials active in ethylene polymerisation without need of aluminum alkyl cocatalyst.
Texto completo:
1
Colección:
01-internacional
Base de datos:
MEDLINE
Asunto principal:
Titanio
/
Cloruros
/
Dióxido de Silicio
/
Polietileno
/
Etilenos
Idioma:
En
Revista:
Macromol Rapid Commun
Año:
2011
Tipo del documento:
Article
País de afiliación:
Francia
Pais de publicación:
Alemania