One approach to cyclic carbonates via a three-component cyclization of phenacyl bromide, CO2, and aldehyde.

Yan, Peng; Tan, Xueqin; Jing, Huanwang; Duan, Shuhui; Wang, Xiaoxuan; Liu, Zhongli

Yan, Peng; Tan, Xueqin; Jing, Huanwang; Duan, Shuhui; Wang, Xiaoxuan; Liu, Zhongli.

Afiliación

Yan P; State Key Laboratory of Applied Organic Chemistry, College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou 730000, Gansu, People's Republic of China.

J Org Chem ; 76(8): 2459-64, 2011 Apr 15.

Article en En | MEDLINE | ID: mdl-21401088

RESUMEN

A three-component cyclization reaction was designed for synthesizing cyclic carbonates in a single operation from phenacyl bromide, CO(2), and aldehyde in the presence of lithium diisopropylamide (LDA). These novel reactions were achieved under extremely mild conditions to generate the target products in moderate to good yields within 10 min.

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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: J Org Chem Año: 2011 Tipo del documento: Article Pais de publicación: Estados Unidos

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