Reactive adsorption of NO2 at ambient conditions on iron-containing polymer-based porous carbons.
ChemSusChem
; 4(3): 404-12, 2011 Mar 21.
Article
en En
| MEDLINE
| ID: mdl-21290609
Adsorption of NO(2) and retention of NO (the product of NO(2) reduction by carbon) on iron-containing materials prepared from polystyrenesulfonic acid-co-maleic acid iron salt were studied. The surface of the materials was characterized using nitrogen adsorption, XRD, scanning electron microscopy (SEM), transmission electron microscopy (TEM), energy-dispersive X-ray (EDX), and FTIR spectroscopy, and thermogravimetric analysis (TGA). The results showed the positive effects of the pore volume and well-dispersed iron species (Fe(2)O(3), FeSO(4), and FeS) on the performance of carbons as NO(2) adsorbents at room temperature. The retention of NO(2) on the carbon surface takes place either through its reduction to NO by carbon and/or by Fe(2)O(3), FeSO(4), and FeS, or through its reaction with Fe(2)O(3) and/or Fe(OH)(3), leading to the formation of Fe(NO(3))(3). The retention of NO is enhanced on carbons containing iron in the form of α-FeOOH, α-Fe(2)O(3), or γ-FeOOH. The best performance was found on the carbon with α-Fe(2)O(3). Dispersion and the particle size of iron compounds on the carbon surface affect both the adsorption/reduction process of NO(2) and the retention process of NO.
Texto completo:
1
Colección:
01-internacional
Base de datos:
MEDLINE
Asunto principal:
Polímeros
/
Carbono
/
Compuestos de Hierro
/
Dióxido de Nitrógeno
Idioma:
En
Revista:
ChemSusChem
Asunto de la revista:
QUIMICA
/
TOXICOLOGIA
Año:
2011
Tipo del documento:
Article
País de afiliación:
Estados Unidos
Pais de publicación:
Alemania