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The coordination polymer poly[(µ3-3-aminocarbonylpyrazine-2-carboxylato-κ3N1:O2:O2')silver(I)].
Massoud, Al-shima'a A; Langer, Vratislav; Abu-Youssef, Morsy A M; Öhrström, Lars.
Afiliación
  • Massoud AS; Department of Chemical and Biological Engineering, Chalmers University of Technology, SE-41296 Göteborg, Sweden. shimo@chalmers.se
Acta Crystallogr C ; 67(Pt 1): m1-4, 2011 Jan.
Article en En | MEDLINE | ID: mdl-21206069
The title compound, [Ag(C(6)H(4)N(3)O(3))](n) or [Ag(pyzca)](n) (where pyzca is 3-aminocarbonylpyrazine-2-carboxylate), (I), was obtained by silver-catalysed partial hydrolysis of pyrazine-2,3-dicarbonitrile in aqueous solution. The compound has a distorted trigonal-planar coordination geometry around the Ag(I) ion, with each ligand bridging three Ag(I) ions to form a one-dimensional strand of molecules parallel to the b axis. An extensive hydrogen-bond pattern connects these strands to form a three-dimensional network of mog topology.

Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Acta Crystallogr C Año: 2011 Tipo del documento: Article País de afiliación: Suecia Pais de publicación: Estados Unidos

Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Acta Crystallogr C Año: 2011 Tipo del documento: Article País de afiliación: Suecia Pais de publicación: Estados Unidos