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Synthesis, spectroscopic characterization, and observation of massive metal-insulator transitions in nanowires of a nonstoichiometric vanadium oxide bronze.
Patridge, Christopher J; Wu, Tai-Lung; Jaye, Cherno; Ravel, Bruce; Takeuchi, Esther S; Fischer, Daniel A; Sambandamurthy, G; Banerjee, Sarbajit.
Afiliación
  • Patridge CJ; Department of Chemistry, University at Buffalo, Buffalo, New York 14260-3000, USA.
Nano Lett ; 10(7): 2448-53, 2010 Jul 14.
Article en En | MEDLINE | ID: mdl-20509685
Metal-insulator transitions in strongly correlated materials, induced by varying either temperature or dopant concentration, remain a topic of enduring interest in solid-state chemistry and physics owing to their fundamental importance in answering longstanding questions regarding correlation effects. We note here the unprecedented observation of a four-orders-of-magnitude metal-insulator transition in single nanowires of delta-K(x)V(2)O(5), when temperature is varied, which thus represents a rare new addition to the pantheon of materials exhibiting pronounced metal-insulator transitions in proximity to room temperature.

Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Nano Lett Año: 2010 Tipo del documento: Article País de afiliación: Estados Unidos Pais de publicación: Estados Unidos

Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Nano Lett Año: 2010 Tipo del documento: Article País de afiliación: Estados Unidos Pais de publicación: Estados Unidos