Communications: Monovalent ion condensation at the electrified liquid/liquid interface.
J Chem Phys
; 132(17): 171101, 2010 May 07.
Article
en En
| MEDLINE
| ID: mdl-20459149
X-ray reflectivity studies demonstrate the condensation of a monovalent ion at the electrified interface between electrolyte solutions of water and 1,2-dichloroethane. Predictions of the ion distributions by standard Poisson-Boltzmann (Gouy-Chapman) theory are inconsistent with these data at higher applied interfacial electric potentials. Calculations from a Poisson-Boltzmann equation that incorporates a nonmonotonic ion-specific potential of mean force are in good agreement with the data.
Texto completo:
1
Colección:
01-internacional
Base de datos:
MEDLINE
Asunto principal:
Agua
/
Electricidad
/
Dicloruros de Etileno
Idioma:
En
Revista:
J Chem Phys
Año:
2010
Tipo del documento:
Article
País de afiliación:
Estados Unidos
Pais de publicación:
Estados Unidos